INTRODUCTION OF LABORATORY

Chemistry of group-13 elements Group-13 elements such as B and Al are the rare elements that form icosahedral cluster structures. We found that the character of such clusters in solids can be converted from covalent to metallic, by introduction of central atoms. By using an electrostatic levitation system, we discovered that liquid boron is a semiconductor. Searches for new cluster superconductors and new cluster molecules are in progress, from calculation and experiments. Quasicrystals Quasicrystal are lattice structures that lacks periodic symmetry, like a Penrose lattice with 5-fold symmetry. We are searching for new three-dimensional quasicrystals that contains icosahedral clusters of group 13-elements. We investigate the properties of those quasicrystals and related structures (approximant crystals) from theory and experiments. The final goal of us is the first discovery of semiconducting quasicrystals. Search for new thermoelectric materials Thermoelectric materials are solids that convert heat and electricity. However, determination of the most promising material family is difficult, since thermoelectric properties changes dramatically by varying carrier density, impurity doping and microstructures. By first-principles calculations and experiments, we are investigating thermoelectric properties of various complex intermetallic compounds including quasicrystals and incommensurate compounds. We succeeded in discovery of new thermoelectric materials RuGa2 and FeGeγ. By collaboration with information scientists, we are gathering a big data of experiments in past literatures, and applying machine learning techniques to accelerate research and development

KAORU KIMURA LAB. research

 

ボロン系とアルミ系正20面体クラスター固体の多重殻構造の比較アルミ系では、共有結合を持つボロン系で空になっているサイト(点線の円)に原子が存在し金属結合となっている

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IMPRESSION IN THE AGE OF TWENTIES IS ENTIRE LIFE’S TREASURE IN THE FIELD OF SCIENCE.

The discovery of "Quasicrystal" gave a great impression to me, and I have continued to investigate it until now. It takes 27 years from the first discovery in 1984 to get Novel Prize in 2011 after establishment as a big concept of solid state structure, which takes a place beside "Crystal" and "Amorphous". In "Quasicrystal", "Semiconductor" and "Insulator" have not yet been discovered. It is remaining as a basic problem in the solid state physics, whether they exist or not. On the other hand, the development of high performance "thermoelectric material" has a potential to be a key technology, which can contribute to the energy problem and the environmental one. We are proposing that "Semiconducting Quasicrystal" should be a great candidate for thermoelectric material.

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